Carbon-carbon double bond as substituents: Free radical halogenations of alkenes, comparision of free radical substitution with free radical addition, free radical substitution in alkenes, orientation and reactivity, allylic rearrangements. SCROLL DOWN TO THE BOTTOM OF THIS PAGE FOR ACTUAL NOTES.…
Electrophillic and free radicals addition: Reactions at carbon-carbon, double bond, electrophile, hydrogenation, heat of hydrogenation and stability of alkenes, markownikoff rule, addition of hydrogen halides, addition of hydrogen bromides, peroxide effect, electrophillic addition, mechanism, rearrangement, absence of hydrogen exchange, orientation…
Dehydrohalogenation of alkyl halides: 1,2 elimination, kinetics, E2 and E1 mechanism, elimination via carbocation, evidence for E2 mechanism, absence of rearrangement isotope effect, absence hydrogen exchange, the element effect, orientation and reactivity, E2 versus E1, elimination versus substitution,dehydration of alcohol,…
Dehydrohalogenation of alkyl halides: 1,2 elimination, kinetics, E2 and E1 mechanism, elimination via carbocation, evidence for E2 mechanism, absence of rearrangement isotope effect, absence hydrogen exchange, the element effect, orientation and reactivity, E2 versus E1, elimination versus substitution,dehydration of alcohol,…
Dehydrohalogenation of alkyl halides: 1,2 elimination, kinetics, E2 and E1 mechanism, elimination via carbocation, evidence for E2 mechanism, absence of rearrangement isotope effect, absence hydrogen exchange, the element effect, orientation and reactivity, E2 versus E1, elimination versus substitution,dehydration of alcohol,…
Dehydrohalogenation of alkyl halides: 1,2 elimination, kinetics, E2 and E1 mechanism, elimination via carbocation, evidence for E2 mechanism, absence of rearrangement isotope effect, absence hydrogen exchange, the element effect, orientation and reactivity, E2 versus E1, elimination versus substitution,dehydration of alcohol,…
Nuclophilic aliphatic substitution mechanism: Nucleophiles and leaving groups,kinetics of second and first order reaction, mechanism and kinetics of SN2reactions. Stereochemistry and steric hindrance, role of solvents, phase transfercatalysis, mechanism and kinetics of SN1 reactions, stereochemistry, carbocationand their stability, rearrangement of…
Nuclophilic aliphatic substitution mechanism: Nucleophiles and leaving groups,kinetics of second and first order reaction, mechanism and kinetics of SN2reactions. Stereochemistry and steric hindrance, role of solvents, phase transfercatalysis, mechanism and kinetics of SN1 reactions, stereochemistry, carbocationand their stability, rearrangement of…
Nuclophilic aliphatic substitution mechanism: Nucleophiles and leaving groups, kinetics of second and first order reaction, mechanism and kinetics of SN2 reactions. Stereochemistry and steric hindrance, role of solvents, phase transfer catalysis, mechanism and kinetics of SN1 reactions, stereochemistry, carbocation and…
